酸性络蓝K双波长信号系数光度法测定钙镁

基于在氢氧化钠溶液中,钙、镁均与酸性络蓝K(ACBK)形成暗红色配合物,提出了测定钙和镁的双波长信号系数光度法.该法不仅消除了钙、镁之间的吸收干扰,且消除了一定量的共存离子的干扰.利用褪色法与生色法的吸光度之和作为信号吸光度,使方法的灵敏度大为提高.测定钙、镁总量时,分别用钙、镁吸收曲线正峰与负峰上的等吸收波长470.5 nm(λPa)及559.5 nm(λNa)处测定吸光度APa和ANa,求得总量的信号系数fs为2.439.于λPa470.5 nm处测得任一浓度钙、镁试液的吸光度APa′,其信号吸光度As=fsAλPa′.测定镁时,以试剂ACBK褪色对钙配合物生色的完全相消干扰的波长539 nm(Pa)作为测定波长,负峰波长583 nm为Na.按相同方法测得镁的信号系数fs为4.148.     

对三氟甲基苯甲酸和2，2′-联吡啶双核铽配合物的合成、晶体结构及发光性质

A new dinuclear complex [Tb₂(BA)₆(2,2′-bipy)₂] (BA=4-(trifluoromethyl)benzoic acid, 2,2′-bipy=2,2′-bipyridine) has been synthesized. The complex was characterized by X-ray single-crystal structure analysis. The complex is a dimer with an inversion center. In the complex, two Tb3+ ions are linked by four carboxylate groups of BA ligands in bridging-bidentate coordination mode. Each Tb³⁺ ion is eight-coordinated with two nitrogen atoms from one 2,2′-bipy molecule, four oxygen atoms from four bridging-bidentate BA ligands and two oxygen atoms from one chelating-bidentate BA ligand. Intermolecular hydrogen bonds are formed in the crystal. The complex exhibits strong green fluorescence under ultraviolet light and the fluorescence spectrum consists of four lines peaking at 489, 545, 584 and 620 nm, which are corresponding to the ⁵D₄→⁷F_j (j=6～3) transitions of Tb³⁺ ion, respectively. CCDC: 727763.     

The cage effect on assembly of cyclic-bis-(zinc porphyrin) with 5,15-dipyridylporphyrin

An inclusion complex of cyclic bis(zinc porphyrin) 1 with 5,15-dipyridylporphyrin derivative 3 has been designed and constructed. The complex formation is induced by Zn-N coordination, and is robust (Kassoc ~ 106 L/mol) due to the presence of the cage effect of cyclic bis(zinc porphyrin). The cage-like complex as an entity is stable enough, and also convenient to achieve relative movement between the bis(zinc porphyrin) host and the dipyridylporphyrin guest connected by Zn-N coordination. The characteristic...     

Synthesis, characterization and DNA-binding studies of ruthenium(II) mixed-ligand complexes containing dipyrido[1,2,5]oxadiazolo[3,4-b]quinoxaline

A novel ligand dipyrido[1,2,5]oxadiazolo[3,4-b]quinoxaline (dpoq) and its complexes [Ru(bpy)₂(dpoq)]²⁺ and [Ru(phen)₂(dpoq)]²⁺ (bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline) have been synthesized and characterized by elemental analysis, electrospray mass spectra and ¹H NMR. The interaction of Ru(II) complexes with calf thymus DNA (CT-DNA) was investigated by absorption spectroscopy, fluorescence spectroscopy, thermal denaturation and viscosity measurements. Results suggest that two Ru(II) complexes bind to DNA via an intercalative mode.     

变系数反馈移位寄存器及其序列的几个性质

本文给出了一类新的密钥流生成器一变系数反馈移位寄存器,得到了该密钥流生成器序列的几个重要的密码学性质,并在文中给出了严格的数学证明。     

胍盐离子液体捕获CO2温室气体的机理

通过量子力学与分子动力学对胍盐离子液体的模拟表明,胍阳离子与氯负离子之间存在较强的相互作用,其相互作用能约为-109．216kcal／m01．从能量与几何分布可见,两种空间分布方式中最稳定构象为Middle作用模式．径向分布函数也验证了这一结论．C02含量的不断增加并没有对离子液体的结构产生影响,而是被离子液体的空腔捕获．     

探地雷达数值模拟中广义完全匹配层吸收边界条件的模拟分析

探讨探地雷达正演模拟中,应用广义完全匹配层(GPML)吸收边界条件时的模拟效果.利用时域有限差分(FDTD)法将麦克斯韦方程离散化,再采用Mur超吸收边界条件和GPML吸收边界条件吸收向外的电磁波,模拟充水岩溶的雷达图像;同时,采用GPML吸收边界条件模拟多个圆柱体异常模型和倾斜界面异常模型的探地雷达剖面图像.对模拟结果的分析可知,GPML吸收边界条件可有效地吸收向外的电磁波,其吸收效果优于Mur超吸收边界条件,在探地雷达的应用中可推广应用.     

纳米钯催化剂对甲醇的电催化氧化

采用水热法,以甲醛作还原剂还原Pd2+-EDTA络合物,制得钛基纳米钯颗粒电极(nanoPd/Ti).扫描电子显微镜(SEM)显示,纳米钯颗粒直径约为60 nm,形成三维立体网状结构.在碱性溶液中,循环伏安及交流阻抗测试分别表明:nanoPd/Ti电极对甲醇氧化有极高的阳极电流、较低的起始氧化电位和较强的抗CO毒化能力.在nanoPd/Ti电极上甲醇电氧化反应的阻抗值较低,增加甲醇浓度,电极阻抗更低.电极对甲醇氧化具有极好的电催化活性.     

单轴荷载下饱水岩石静态和动态抗压强度的细观力学分析

由于单轴荷载下饱水岩石的动态力学特性与静态力学特性存在很大差异,从宏观上进行力学分析 存在局限性。根据岩石受压全应力应变曲线的细观机制,分析了静态及动态单轴荷载条件下孔隙水影响饱水 岩石裂纹扩展的情况。在静态单轴压缩条件下,初始裂隙受压使自由水产生孔隙水压力,自由水对翼裂纹有 向外挤压的应力,促进裂纹扩展。在动态单轴压缩条件下,自由水会产生粘结力,抑制裂纹扩展。根据翼裂纹 受压扩展原理,推导出饱水单轴条件下动态抗压强度、静态抗压强度的计算公式,在相同断裂韧度下,饱水岩 石静态抗压强度风干岩石静态抗压强度饱水岩石动态抗压强度。对自然风干和饱水砂岩进行单轴静态、 动态压缩实验,结果与理论模型的结果相符。     

取代基对多取代氮苄叉苯胺化合物分子桥键（CH=N）的13C NMR和1H NMR的影响

Fifty-three samples of multi-substituted benzylideneanilines XArCH=NArYs (abbreviated XBAYs) were synthesized and their NMR spectra were determined. An extensional study of substituent effects on the ¹H NMR chemical shifts (^δH(CH=N)) and ¹³C NMR chemical shifts (^δC(CH=N)) of the CH=N bridging group from di-substituted to multi-substituted XBAYs was made based on a total of 182 samples of XBAYs, together with the NMR data of other 129 samples of di-substituted XBAYs quoted from literatures. The results show that the substituent specific cross-interaction effect parameter (Δ(Σσ)²)plays an important role in quantifying the ^δC(CH=N) values of XBAYs, but it is negligible for quantifying the ^δH(CH=N) values; the other substituent parameters also present different influences on the ^δC(CH=N) and ^δH(CH=N). On the whole, the contributions of X and Y to the ^δC(CH=N) of XBAYs are balanced, but the ^δH(CH=N) values of XBAYs mainly rely on the contributions of X.